POWER architecture can switch between BE/LE via a special purpose register (SPR). This can even be done to support mixing BE/LE threads on the core. The software complexity of managing that, though, has made them decide to enable the entire OS as BE or LE. One cool thing is that the support will be extended so that the chips can support running either BE or LE guest VMs natively.
(It's been a long time since I last typed "PowerPC", gave me a strange feeling of nostalgia...)